articleAdvanced Functional MaterialsMar 12, 2024Closed access

Fluorenone‐Based Covalent Triazine Frameworks/Twinned Zn 0.5 Cd 0.5 S S‐scheme Heterojunction for Efficient Photocatalytic H 2 Evolution

South China Agricultural University · Ministry of Agriculture and Rural Affairs · +2 more institutions

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Abstract

Abstract Photocatalytic hydrogen evolution reaction (HER) is a very promising and sustainable technology, yet precisely exploring effective HER photocatalysts remains a critical challenge due to the rapid charge recombination. In this work, a brand‐new S‐scheme heterojunction is successfully designed and constructed by in situ growth of twinned Zn 0.5 Cd 0.5 S Solid Solution (CZS) on a novel fluorenone‐based covalent triazine framework (FOCTF). The S‐scheme heterojunctions is identified via in situ irradiation XPS, and electron spin resonance, which can greatly improve the photocatalytic HER rate and stability. Under illumination, the highest photocatalytic HER rate of well‐designed CZS‐FOCTF is 247.62 mmolg…

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