Vinyl‐Group‐Anchored Covalent Organic Framework for Promoting the Photocatalytic Generation of Hydrogen Peroxide

Abstract The artificial photosynthesis of H 2 O 2 from water and oxygen using semiconductor photocatalysts is attracting increasing levels of attention owing to its green, environmentally friendly, and energy‐saving characteristics. Although covalent organic frameworks (COFs) are promising materials for promoting photocatalytic H 2 O 2 production owing to their structural and functional diversity, they typically suffer from low charge‐generation and ‐transfer efficiencies as well as rapid charge recombination, which restricts their use as catalysts for photocatalytic H 2 O 2 production. Herein, we report a strategy for anchoring vinyl moieties to a COF skeleton to facilitate charge separation and migration,…

• NN
  National Natural Science Foundation of China

  Awards: 22032002, 21972021, 2021YFA1502100, 21972021, 52090033, 52201006, 22032002, 52201006, 52090033
• HE
  Higher Education Discipline Innovation Project

  Award: D16008