articleJournal of the American Chemical SocietyMar 18, 2024Closed access

Single-Atom Ni Supported on TiO 2 for Catalyzing Hydrogen Storage in MgH 2

Beihang University · Jimei University · +1 more institution

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Abstract

As an efficient and clean energy carrier, hydrogen is expected to play a key role in future energy systems. However, hydrogen-storage technology must be safe with a high hydrogen-storage density, which is difficult to achieve. MgH2 is a promising solid-state hydrogen-storage material owing to its large hydrogen-storage capacity (7.6 wt %) and excellent reversibility, but its large-scale utilization is restricted by slow hydrogen-desorption kinetics. Although catalysts can improve the hydrogen-storage kinetics of MgH2, they reduce the hydrogen-storage capacity. Single-atom catalysts maximize the atom utilization ratio and the number of interfacial sites to boost the catalytic activity, while easy aggregation at…

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158
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17.22
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100%
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57
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Authors

6

Topics & keywords

Keywords
  • Dehydrogenation
  • Hydrogen storage
  • Catalysis
  • Chemistry
  • Hydrogen
  • Desorption
  • Kinetics
  • Activation energy
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