articleJournal of the American Chemical SocietyApr 3, 2024Closed access

Revolutionizing CO 2 Electrolysis: Fluent Gas Transportation within Hydrophobic Porous Cu 2 O

Beijing Institute of Technology · Chinese Academy of Sciences · +6 more institutions

PubMed
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Abstract

The success of electrochemical CO2 reduction at high current densities hinges on precise interfacial transportation and the local concentration of gaseous CO2. However, the creation of efficient CO2 transportation channels remains an unexplored frontier. In this study, we design and synthesize hydrophobic porous Cu2O spheres with varying pore sizes to unveil the nanoporous channel’s impact on gas transfer and triple-phase interfaces. The hydrophobic channels not only facilitate rapid CO2 transportation but also trap compressed CO2 bubbles to form abundant and stable triple-phase interfaces, which are crucial for high-current-density electrocatalysis. In CO2 electrolysis, in situ spectroscopy and density…

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