articleAngewandte Chemie International EditionApr 10, 2024HYBRID OA

Silica Confinement for Stable and Magnetic Co−Cu Alloy Nanoparticles in Nitrogen‐Doped Carbon for Enhanced Hydrogen Evolution

National Institute for Materials Science · Zhejiang University · +7 more institutions

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Abstract

Abstract Ammonia borane (AB) with 19.6 wt % H 2 content is widely considered a safe and efficient medium for H 2 storage and release. Co‐based nanocatalysts present strong contenders for replacing precious metal‐based catalysts in AB hydrolysis due to their high activity and cost‐effectiveness. However, precisely adjusting the active centers and surface properties of Co‐based nanomaterials to enhance their activity, as well as suppressing the migration and loss of metal atoms to improve their stability, presents many challenges. In this study, mesoporous‐silica‐confined bimetallic Co−Cu nanoparticles embedded in nitrogen‐doped carbon (Co x Cu 1−x @NC@mSiO 2 ) were synthesized using a facile mSiO 2 ‐confined…

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112
total citations
FWCI
12.21
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100%
References
83
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Authors

10

Topics & keywords

Keywords
  • Bimetallic strip
  • Nanomaterial-based catalyst
  • Catalysis
  • Materials science
  • Carbon fibers
  • Noble metal
  • Mesoporous silica
  • Nanoparticle
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