articleAngewandte Chemie International EditionApr 12, 2024BRONZE OA

Regulating the Topology of Covalent Organic Frameworks for Boosting Overall H 2 O 2 Photogeneration

Shandong Normal University · Ministry of Education · +3 more institutions

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Abstract

Abstract Photocatalytic oxygen reduction reactions and water oxidation reactions are extremely promising green approaches for massive H 2 O 2 production. Nonetheless, constructing effective photocatalysts for H 2 O 2 generation is critical and still challenging. Since the network topology has significant impacts on the electronic properties of two dimensional (2D) polymers, herein, for the first time, we regulated the H 2 O 2 photosynthetic activity of 2D covalent organic frameworks (COFs) by topology. Through designing the linking sites of the monomers, we synthesized a pair of novel COFs with similar chemical components on the backbones but distinct topologies. Without sacrificial agents, TBD‐COF with cpt…

Citation impact

141
total citations
FWCI
15.30
Percentile
100%
References
54
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Authors

7

Topics & keywords

Keywords
  • Boosting (machine learning)
  • Covalent bond
  • Photochemistry
  • Chemistry
  • Topology (electrical circuits)
  • Materials science
  • Organic chemistry
  • Computer science
UN Sustainable Development Goals
  • Affordable and clean energy
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