articleAdvanced Energy MaterialsApr 12, 2024BRONZE OA

Interfacial Modification of NiO x for Highly Efficient and Stable Inverted Perovskite Solar Cells

Ingenierie des Materiaux polymeres · Zhejiang University · +4 more institutions

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Abstract

Abstract Nickel oxide is one of the most promising hole‐transporting materials in inverted perovskite solar cells (PSCs) but suffers from undesired reactions with perovskite which leads to limited device performance and stability. Self‐assembled monolayers (SAMs) are demonstrated to effectively optimize the NiO x /perovskite interface, but the significance of the compactness of the SAM at the interface is less investigated. Here, a series of methoxy‐substituted triphenylamine functionalized benzothiadiazole (TBT) based SAM molecules, TBT‐BA, TBT‐FBA, and TBT‐DBA, with benzoic acid, 2‐fluorobenzoic acid and isophthalic acids as anchoring groups are used to modify NiO x . TBT‐BA with the simplest structure is…

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141
total citations
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26.95
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100%
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54
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Authors

10

Topics & keywords

Keywords
  • Non-blocking I/O
  • Perovskite (structure)
  • Materials science
  • Passivation
  • Nickel oxide
  • Triphenylamine
  • Chemical engineering
  • Oxide
UN Sustainable Development Goals
  • Affordable and clean energy
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