articleAdvanced Functional MaterialsApr 21, 2024BRONZE OA

Hydrogen Bond Network Regulation in Electrolyte Structure for Zn‐based Aqueous Batteries

Shaanxi University of Science and Technology · Fudan University · +2 more institutions

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Abstract

Abstract Electrolyte regulation in Zn‐based aqueous batteries (ZABs) has been extensively reported, and a broad range of strategies has been proposed. However, there is currently a lack of systematic summaries and a comprehensive understanding of the impact of hydrogen bond (H‐bond) networks on electrolyte performance. This work presents the electrolyte structure model, encompassing solvation structure, electrolyte/Zn anode interface, and H‐bond network. Through emphasizing and summarizing the reconstruction, strengthening, and breaking of the H‐bond network within the electrolyte structure, various specific regulation strategies are identified, such as high Gutmann donor number solvent, organic co‐solvent,…

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