articleJournal of Molecular StructureApr 30, 2024HYBRID OA

A new type Co(II)-based photocatalyst for the nitrofurantoin antibiotic degradation

RXRuifang XiangCZChangxin ZhouYLYichen LiuTQTianrui QinDLDuqingcuo Li

Lanzhou Jiaotong University · King Saud University · +1 more institution

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Abstract

Coordination polymers (CPs) are a special class of multidimensional materials that can be employed for the photocatalytic degradation of antibiotics in wastewater. In this paper, a new Co(II)-based coordination polymer with the molecular formula {[Co(H2L)(dpa)(H2O)]·H2O}n (1), (H4L = 1,1′:2′,1"-triphenyltetracarboxylic acid, dpa = 1,2-di(pyridin-4-yl)diazene) was synthesized and characterized. Single-crystal x-ray diffraction results showed that 1 formed a 2D layered structure, which was stacked into a three-dimensional (3D) supramolecular structure through hydrogen-bonding interactions. In addition, the results of the photocatalytic experiments showed that 1 possesses good photocatalytic activity at…

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114
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18.36
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100%
References
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Authors

8

Topics & keywords

Topics
Keywords
  • Photocatalysis
  • Chemistry
  • Hydrogen bond
  • Supramolecular chemistry
  • Nitrofurantoin
  • Coordination polymer
  • Degradation (telecommunications)
  • Polymer
UN Sustainable Development Goals
  • Clean water and sanitation
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