Visible Light-Induced Reactions of Diazo Compounds and Their Precursors

In recent years, visible light-induced reactions of diazo compounds have attracted increasing attention in organic synthesis, leading to improvement of existing reactions, as well as to the discovery of unprecedented transformations. Thus, photochemical or photocatalytic generation of both carbenes and radicals provide milder tools toward these key intermediates for many valuable transformations. However, the vast majority of the transformations represent new reactivity modes of diazo compounds, which are achieved by the photochemical decomposition of diazo compounds and photoredox catalysis. In particular, the use of a redox-active photocatalysts opens the avenue to a plethora of radical reactions. The…

• WF
  Welch Foundation

  Award: AT-0041
• NI
  National Institute of General Medical Sciences

  Award: GM120281
• DO
  Division of Chemistry

  Award: CHE-2246075