articleJournal of the American Chemical SocietyMay 30, 2024Closed access

Efficient Photocatalytic CO 2 Reduction in Ellagic Acid–Based Covalent Organic Frameworks

Chinese Academy of Sciences · Fujian Institute of Research on the Structure of Matter · +3 more institutions

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Abstract

Employing covalent organic frameworks (COFs) for the photocatalytic CO2 reduction reaction (CDRR) to generate high-value chemical fuels and mitigate greenhouse gas emissions represents a sustainable catalytic conversion approach. However, achieving superior photocatalytic CDRR performance is hindered by the challenges of low charge separation efficiency, poor stability, and high preparation costs associated with COFs. Herein, in this work, we utilized perfluorinated metallophthalocyanine (MPcF16) and the organic biomolecule compound ellagic acid (EA) as building blocks to actualize functional covalent organic frameworks (COFs) named EPM-COF (M = Co, Ni, Cu). The designed EPCo-COF, featuring cobalt metal active…

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