articleACS NanoJul 31, 2024Closed access

Understanding the Sodium Storage Behavior of Closed Pores/Carbonyl Groups in Hard Carbon

Central South University of Forestry and Technology · Central South University · +1 more institution

PubMed
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Abstract

Hard carbon (HC) is a promising anode material for sodium-ion batteries. However, the intrinsic relationship between the closed pores/surface groups and sodium storage performance has been unclear, leading to difficulties in targeted regulation. In this study, renewable tannin extracts were used as raw materials to prepare HC anodes with abundant tunable closed pores and carbonyl groups through a pyrolytic modulation strategy. Combining ex situ characterizations reveals that closed pores and carbonyl groups are regulated by the pyrolytic process. Further, it is demonstrated that the plateau region is mainly contributed by the closed pores; highly stable fluorine-rich solid electrolyte interphase compositions…

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