articleAdvanced MaterialsJul 31, 2024Closed access

Confining Iodine into Metal‐Organic Framework Derived Metal‐Nitrogen‐Carbon for Long‐Life Aqueous Zinc‐Iodine Batteries

Yangzhou University · Tsinghua–Berkeley Shenzhen Institute · +1 more institution

PubMed
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Abstract

Aqueous zinc-iodine batteries (AZIBs) are highly appealing for energy requirements owing to their safety, cost-effectiveness, and scalability. However, the inadequate redox kinetics and severe shuttling effect of polyiodide ions impede their commercial viability. Herein, several Zn-MOF-derived porous carbon materials are designed, and the further preparation of iron-doped porous carbon (Fe-N-C, M9) with varied Fe doping contents is optimized based on a facile self-assembly/carbonization approach. M9, with atomic Fe coordinated to nitrogen atoms, is employed as an efficient cathode host for AZIBs. Functional modifications of porous carbon hosts involving the doping species and levels are investigated. The…

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202
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100%
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Authors

8

Topics & keywords

Keywords
  • Materials science
  • Aqueous solution
  • Carbon fibers
  • Adsorption
  • Carbonization
  • Chemical engineering
  • Inorganic chemistry
  • Zinc
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