Wrinkled metal-organic framework thin films with tunable Turing patterns for pliable integration

Flexible integration spurs diverse applications in metal-organic frameworks (MOFs). However, current configurations suffer from the trade-off between MOF loadings and mechanical compliance. We report a wrinkled configuration of MOF thin films. We established an interfacial synthesis confined and controlled by a polymer topcoat and achieved multiple Turing motifs in the wrinkled thin films. These films have complete MOF surface coverage and exhibit strain tolerance up to 53.2%. The enhanced mechanical properties allow film transfer onto various substrates. We obtained membranes with large H 2 /CO 2 selectivity (41.2) and high H 2 permeance (8.46 × 10 3 gas permeation units), showcasing negligible defects after…