articleNature CommunicationsOct 4, 2024GOLD OA

Enhanced charge carrier transport and defects mitigation of passivation layer for efficient perovskite solar cells

Institute of Semiconductors · University of Chinese Academy of Sciences · +5 more institutions

PubMed
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Abstract

Surface passivation has been developed as an effective strategy to reduce trap-state density and suppress non-radiation recombination process in perovskite solar cells. However, passivation agents usually own poor conductivity and hold negative impact on the charge carrier transport in device. Here, we report a binary and synergistical post-treatment method by blending 4-tert-butyl-benzylammonium iodide with phenylpropylammonium iodide and spin-coating on perovskite surface to form passivation layer. The binary and synergistical post-treated films show enhanced crystallinity and improved molecular packing as well as better energy band alignment, benefiting for the hole extraction and transfer. Moreover, the…

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