Artificial photosynthetic system for diluted CO2 reduction in gas-solid phase

Rational design of robust photocatalytic systems to direct capture and in-situ convert diluted CO2 from flue gas is a promising but challenging way to achieve carbon neutrality. Here, we report a new type of host-guest photocatalysts by integrating CO2-enriching ionic liquids and photoactive metal-organic frameworks PCN-250-Fe2M (M = Fe, Co, Ni, Zn, Mn) for artificial photosynthetic diluted CO2 reduction in gas-solid phase. As a result, [Emim]BF4(39.3 wt%)@PCN-250-Fe2Co exhibits a record high CO2-to-CO reduction rate of 313.34 μmol g−1 h−1 under pure CO2 atmosphere and 153.42 μmol g−1 h−1 under diluted CO2 (15%) with about 100% selectivity. In scaled-up experiments with 1.0 g catalyst and natural sunlight…

• NN
  National Natural Science Foundation of China

  Award: 22178077
• CP
  China Postdoctoral Science Foundation
• NS
  Natural Science Foundation of Shandong Province

  Award: ZR2022MB126