The breakthrough of oxide pathway mechanism in stability and scaling relationship for water oxidation

An in-depth understanding of electrocatalytic mechanisms is essential for advancing electrocatalysts for the oxygen evolution reaction (OER). The emerging oxide pathway mechanism (OPM) streamlines direct O-O radical coupling, circumventing the formation of oxygen vacancy defects featured in the lattice oxygen mechanism (LOM) and bypassing additional reaction intermediates (*OOH) inherent to the adsorbate evolution mechanism (AEM). With only *O and *OH as intermediates, OPM-driven electrocatalysts stand out for their ability to disrupt traditional scaling relationships while ensuring stability. This review compiles the latest significant advances in OPM-based electrocatalysis, detailing design principles,…

• NN
  National Natural Science Foundation of China

  Awards: 22361162665, 22025208, 22279075
• NS
  Natural Science Foundation of Shandong Province

  Award: ZR2020YQ09