articleAdvanced MaterialsOct 18, 2024BRONZE OA

Construction of COF/COF Organic S‐Scheme Heterostructure for Enhanced Overall Water Splitting

Harbin University of Science and Technology · Catalytic Materials (United States)

PubMed
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Abstract

Abstract Covalent organic frameworks (COFs) as a new type of photocatalysts have shown unique advantages in visible‐light‐driven hydrogen evolution, while the reported overall water‐splitting systems are still very rare among various COF‐based photocatalysts. Herein, two COFs are integrated to construct a type of organic S‐scheme heterojunction for improved overall water splitting. In this system, TpBpy‐COF and COF‐316 serve as H 2 ‐ and O 2 ‐evolving components, respectively, which are combined through π–π interaction between conjugated aromatic rings. By introducing ultra‐small Pt nanoparticles (NPs) into the pores of the TpBpy‐COF nanosheets (NS), the resultant COF‐316/Pt@TpBpy‐COF NS heterostructure…

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