articleNature CommunicationsNov 6, 2024GOLD OA

Electronic and magnetic excitations in La3Ni2O7

Fudan University · State Key Laboratory of Surface Physics · +12 more institutions

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Abstract

High-temperature superconductivity was discovered in the pressurized nickelate La3Ni2O7 which has a unique bilayer structure and mixed valence state of nickel. The properties at ambient pressure contain crucial information of the fundamental interactions and bosons mediating superconducting pairing. Here, using X-ray absorption spectroscopy and resonant inelastic X-ray scattering, we identified that Ni 3 $${d}_{{x}^{2}-{y}^{2}}$$ , Ni 3 $${d}_{{z}^{2}}$$ , and ligand oxygen 2p orbitals dominate the low-energy physics with a small charge-transfer energy. Well-defined optical-like magnetic excitations soften into quasi-static spin-density-wave ordering, evidencing the strong electronic correlation and rich…

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