Surface restructuring and predictive design of heterogeneous catalysts

Heterogeneous catalysts, which often consist of metal nanoparticles loaded on supports such as metal oxides, can undergo several types of restructuring under reaction and catalytic conditions. Advanced characterizations now allow the surface structure of a catalyst in a gas phase to be determined to some extent. Metal nanoparticles may experience changes in shape, surface structure and composition, and atomic packing in response to the pressure of a reactant or product gas, temperature, and reaction between the catalyst surface and gas. Metal oxide supports can partially or fully encapsulate metal nanoparticles, altering their electronic structure and reactivity. Restructuring is a main approach to creating…