articleIndustrial Crops and ProductsJan 8, 2025GOLD OA

Constructing a highly sensitive SERS sensor based on necklace-like CNC/ZIF-8/Ag to detect and photo-degrade diquat in green tea leaves

Wuhan Institute of Technology · Nanjing Institute of Technology

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Abstract

Surface-enhanced Raman spectroscopy (SERS) has been perceived as a valuable tool in ensuring food safety due to its rapid and intuitive nature. In this study, we demonstrate a novel cellulose-ZIF-8-noble metal nanostructure as a SERS substrate for the analysis of pesticide residues in food. Cellulose nanocrystal (CNC) acting as a scaffold, we systematically integrate ZIF-8 and Ag nanoparticles to fabricate tailored necklace-like CNC/ZIF-8/Ag core/shell nanostructures. SERS analysis reveals the CNC/ZIF-8/Ag presents an high enhancement factor of 6.39 × 10 4 , a low limit of detection (LOD) of 10 −9 mol/L, and a relative standard deviation of 10.24 % across 20 substrate batches for 4-mercaptobenzoic acid,…

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