Metal‐Modified Zr‐MOFs with AIE Ligands for Boosting CO 2 Adsorption and Photoreduction
Jilin University · Jilin International Studies University · +4 more institutions
Abstract
Abstract The design and synthesis of metal–organic frameworks (MOFs) with outstanding light‐harvesting and photoexcitation for artificial photocatalytic CO 2 reduction is an attractive but challenging task. In this work, a novel aggregation‐induced emission (AIE)‐active ligand, tetraphenylpyrazine (PTTBPC) is proposed and utilized for the first time to construct a Zr‐MOF photocatalyst via coordination with stable Zr‐oxo clusters. Zr‐MOF is featured by a scu topology with a two‐fold interpenetrated framework, wherein the PTTBPC ligands enable strong light‐harvesting and photoexcitation, while the Zr‐oxo clusters facilitate CO 2 adsorption and activation, as well as offer potential sites for further metal…
Citation impact
- FWCI
- 19.19
- Percentile
- 100%
- References
- 82
Authors
12- BWBolun Wang
Jilin University, Jilin International Studies University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
- WLWen Li
Jilin University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
- JLJunmin Liu
Jilin University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
- TGTao Gan
Chinese Academy of Sciences, Shanghai Advanced Research Institute
- SGShiqin Gao
Jilin University, Jilin International Studies University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
Topics & keywords
- Materials science
- Adsorption
- Metal-organic framework
- Metal
- Boosting (machine learning)
- Nanotechnology
- Inorganic chemistry
- Chemical engineering