articleAdvanced Functional MaterialsJan 20, 2025BRONZE OA

Endeavoring a High Amidoxime Utilization Ratio and Adsorption Capacity for Uranium Extraction From Seawater: A Hydrogen Bonding Reconstruction Strategy

Southwest University of Science and Technology · Southern University of Science and Technology · +1 more institution

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Abstract

Abstract Functionalized amidoxime [AO, R−C(NH 2 )═N(OH)] is widely used for uranium extraction from seawater, but increasing the effective functional sites for high AO utilization in adsorbents remains challenging. This study introduces a hydrogen bond reconstruction strategy to enhance uranium extraction efficiency of AO‐modified polyacrylonitrile (PAN) fibers by blending with polyvinyl alcohol (PVA). The PAN/PVA fibers are synthesized via electrospinning, followed by amidoximation on PAN to prepare PAN‐AO/PVA adsorbents. These materials can extract uranyl ions from the uranyl‐carbonate complex in seawater, achieving an adsorption capacity of 21.0 mg g⁻¹ under simulated seawater conditions with 330 ppb…

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