Ultrahigh piezoelectric performances of (K,Na)NbO3 based ceramics enabled by structural flexibility and grain orientation

(K,Na)NbO3-based ceramics are deemed among the most promising lead-free piezoelectric materials, though their overall piezoelectric performance still lags behind the mainstream lead-containing counterparts. Here, we achieve an ultrahigh piezoelectric charge coefficient d33 ∼ 807 pC·N−1, along with a high longitudinal electromechanical coupling factor (k33 ∼ 88%) and Curie temperature (Tc ∼ 245 °C) in the (K,Na)(Nb1-xSbx)O3-Bi0.5Na0.5ZrO3-BiFeO3 (KNN-xSb) system through structural flexibility and grain orientation strategies. Phenomenological models, phase field simulations and high-angle annular dark-field scanning transmission electron microscopy reveal that the structural flexibility originates from the high…

• NN
  National Natural Science Foundation of China

  Awards: 52272104, 52032007
• UO
  University of Science and Technology Beijing

  Award: FRF-IDRY-GD23-001
• FR
  Fundamental Research Funds for the Central Universities

  Award: FRF-IDRY-GD23-001