articleMacromoleculesJan 24, 2025Closed access

High-Strength and Excellent Self-Healing Polyurethane Elastomer Based on Rigid Chain Segment Reinforcement

Guangxi University · Centre National de la Recherche Scientifique · +4 more institutions

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Abstract

Owing to their extensive application scope, elastomers that combine high strength and excellent self-healing efficiency have always attracted significant attention and are still a contradiction. In this study, a novel PU elastomer was prepared by combining rigid poly(amic acid) (PAA) chain segments and 3,3-dithiodipropionic dihydrazide (DPH) containing sextuple hydrogen-bonding units and disulfide bonds. The prepared elastomer exhibited a high tensile strength of 50.1 MPa and a high toughness of 144.2 MJ/m3. The rigid PAA chain segments serve as a rigid framework, significantly enhancing the mechanical strength of the elastomer. Meanwhile, DPH with sextuple hydrogen-bonding units and disulfide bonds enabled…

Citation impact

50
total citations
FWCI
23.36
Percentile
100%
References
42
Citations per year

Authors

8

Topics & keywords

Keywords
  • Reinforcement
  • Elastomer
  • Polyurethane
  • Self-healing
  • Materials science
  • Composite material
  • Chain (unit)
  • Polymer science
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