articleJournal of the American Chemical SocietyJan 28, 2025Closed access

Anion-Modulated Solvation Sheath and Electric Double Layer Enabling Lithium-Ion Storage From −60 to 80 °C

Nanyang Technological University · Tsinghua University · +2 more institutions

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Abstract

Current lithium batteries experience significant performance degradation under extreme temperature conditions, both high and low. Traditional wide-temperature electrolyte designs typically addressed these challenges by manipulating the solvation sheath and selecting solvents with extreme melting/boiling points. However, these solvent-mediated solutions, while effective at one temperature extreme, invariably fail at the opposite end due to the inherent difficulties in maintaining solvent stability across wide temperatures. Herein, we report the use of the main lithium salt to simultaneously address interfacial challenges at both extremely high and low temperatures. This approach is different from the…

Citation impact

61
total citations
FWCI
34.82
Percentile
100%
References
46
Citations per year

Authors

16

Topics & keywords

Keywords
  • Chemistry
  • Ion
  • Lithium (medication)
  • Solvation
  • Layer (electronics)
  • Inorganic chemistry
  • Organic chemistry
UN Sustainable Development Goals
  • Affordable and clean energy
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