MXene-Assisted NiFe sulfides for high-performance anion exchange membrane seawater electrolysis

Anion exchange membrane seawater electrolysis is vital for future large-scale green hydrogen production, however enduring a huge challenge that lacks high-stable oxygen evolution reaction electrocatalysts. Herein, we report a robust OER electrocatalyst for AEMSE by integrating MXene (Ti3C2) with NiFe sulfides ((Ni,Fe)S2@Ti3C2). The strong interaction between (Ni,Fe)S2 and Ti3C2 induces electron distribution to trigger lattice oxygen mechanism, improving the intrinsic activity, and particularly prohibits the dissolution of Fe species during OER process via the Ti-O-Fe bonding effectively, achieving notable stability. Furthermore, the good retention of sulfates and the abundant groups of Ti3C2 provide effective…

• HU
  Heilongjiang University

  Award: 2021-KYYWF-0031
• NN
  National Natural Science Foundation of China

  Awards: 22171074, U20A20250, 22322104
• NK
  National Key Research and Development Program of China