articleACS NanoFeb 5, 2025Closed access

An S-Scheme MOF-on-MXene Heterostructure for Enhanced Photocatalytic Periodate Activation

University of Science and Technology of China · Hefei National Center for Physical Sciences at Nanoscale · +2 more institutions

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Abstract

Fully understanding the periodate (PI) activation system is still a great challenge, which calls for efficient heterogeneous catalysts with a sophisticated structure. Herein, we developed “MOF-on-MXene” heterostructures. By constructing S-scheme heterostructures MXene/Z67450, the internal electric field is generated via the Ti–O–Co bonds at the interface, favoring the excitation of the photogenerated electrons, providing a driving force for accelerating the charge transfer, and enhancing redox performances. Further contributed by the synergy of Ti–O–Co and Co–N4 bonds, the MXene/Z67450 composites exhibit enhanced ability for activating the periodate system to degrade organic pollutants via building a…

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