reviewJournal of the American Chemical SocietyFeb 7, 2025Closed access

Architecting Metal–Organic Frameworks at Molecular Level toward Direct Air Capture

Fujian Normal University · Ingenierie des Materiaux polymeres · +3 more institutions

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Abstract

Escalating carbon dioxide (CO2) emissions have intensified the greenhouse effect, posing a significant long-term threat to environmental sustainability. Direct air capture (DAC) has emerged as a promising approach to achieving a net-zero carbon future, which offers several practical advantages, such as independence from specific CO2 emission sources, economic feasibility, flexible deployment, and minimal risk of CO2 leakage. The design and optimization of DAC sorbents are crucial for accelerating industrial adoption. Metal–organic frameworks (MOFs), with high structural order and tunable pore sizes, present an ideal solution for achieving strong guest–host interactions under trace CO2 conditions. This…

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