Controlling electrocatalytic nitrate reduction efficiency by utilizing dπ–pπ interactions in parallel stacking molecular systems
Ramakrishna Mission Vidyamandira · Government of West Bengal · +2 more institutions
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Abstract
The orientation of β-CuPc favours the overlap of central Cu with the N of parallel molecules, which is the reason behind high electrical conductivity and selectivity in NH 3 production via nitrate reduction, which is impossible in other polymorphs.
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Authors
7Topics & keywords
Topics
Keywords
- Stacking
- Selectivity
- Nitrate
- Reduction (mathematics)
- Molecule
- Conductivity
- Electrical resistivity and conductivity
- Chemistry
UN Sustainable Development Goals
- Affordable and clean energy
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Funding
- ANArthritis National Research Foundation
- NRNational Research Foundation
- DODepartment of Science and Technology, Ministry of Science and Technology, India
- MOMinistry of Electronics and Information technology
- SAScience and Engineering Research BoardAwards: EEQ/2022/001082, CRG/2022/005423, CRG/2022/009427