articleAdvanced Energy MaterialsFeb 13, 2025HYBRID OA

Cd Single Atom as an Electron Mediator in an S‐Scheme Heterojunction for Artificial Photosynthesis of H 2 O 2

City University of Hong Kong · Jilin University · +5 more institutions

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Abstract

Abstract Developing conductor‐mediated S‐scheme heterojunction photocatalysts imitating natural photosynthetic systems emerges as a promising approach to hydrogen peroxide (H 2 O 2 ) production. However, achieving precise coupling between two semiconductors with a charge shuttle and modulating the interfacial interactions still remain a significant bottleneck. Herein, we propose a catalyst architecture with a Cd single atom mediated S‐scheme heterojunction formed by interfacing CdS and TiO 2 nanoparticles. This catalyst exhibits an H 2 O 2 production rate as high as 60.33 µmol g −1 min −1 under UV–vis light irradiation, which is attributed to the efficient charge transport at the interface of CdS and TiO 2…

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