Visible light–triggered depolymerization of commercial polymethacrylates

The reversion of vinyl polymers with carbon-carbon backbones to their monomers represents an ideal path to alleviate the growing plastic waste stream. However, depolymerizing such stable materials remains a challenge, with state-of-the-art methods relying on "designer" polymers that are neither commercially produced nor suitable for real-world applications. In this work, we report a main chain-initiated, visible light-triggered depolymerization directly applicable to commercial polymers containing undisclosed impurities (e.g., comonomers, additives, or dyes). By in situ generation of chlorine radicals directly from the solvent, near-quantitative (>98%) depolymerization of polymethacrylates could be achieved…