articleAngewandte Chemie International EditionMar 11, 2025BRONZE OA

Modulated Multicomponent Reaction Pathway by Pore‐Confinement Effect in MOFs for Highly Efficient Catalysis of Low‐Concentration CO 2

FRFang‐Yu RenCHChaopeng HuWHWen‐Bin HuangLDLing‐Hao DuanYMYun‐Zhu Meng

Nankai University

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Abstract

Abstract The conversion of flue gas CO 2 into high‐value chemicals via multicomponent reactions (MCRs) offers the advantages of atom economy, bond‐formation efficiency and product complexity. However, because of the competition between reaction sequences and pathways among substrates, the efficient synthesize the desired product is a great challenge. Herein, a porous noble‐metal‐free framework ( Cu‐TCA) was synthesized, which can highly effectively catalyze the multicomponent conversion of CO 2 by modulating reaction pathways. The pores with the size of 6.5 Å×6.5 Å in Cu‐TCA selectively permit the entry of propargylamine and CO 2 at simulated flue gas concentrations, At the same time, the larger‐sized…

Citation impact

52
total citations
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21.69
Percentile
100%
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84
Citations per year

Authors

17
  • FR
    Fang‐Yu Ren

    Nankai University

  • CH
    Chaopeng Hu

    Nankai University

  • WH
    Wen‐Bin Huang

    Nankai University

  • LD
    Ling‐Hao Duan

    Nankai University

  • YM
    Yun‐Zhu Meng

    Nankai University

Topics & keywords

Topics
Keywords
  • Catalysis
  • Chemical engineering
  • Materials science
  • Nanotechnology
  • Chemistry
  • Organic chemistry
  • Engineering
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