Singlet‐Oxygen‐Driven Cooperative Photocatalytic Coupling of Biomass Valorization and Hydrogen Peroxide Production Using Covalent Organic Frameworks
Dalian Institute of Chemical Physics · Chinese Academy of Sciences · +1 more institution
Abstract
Abstract Traditional H 2 O 2 photocatalysis primarily depends on photoexcited electrons and holes to drive oxygen reduction and water oxidation, respectively. However, singlet oxygen ( 1 O 2 ), often underappreciated, plays a pivotal role in H 2 O 2 production. Meanwhile, photocatalytic biomass conversion has attracted attention, yet studies combining H 2 O 2 synthesis with biomass valorization remain rare and typically yield low‐value products. Herein, a strategy of photocatalytic valorization of furfuryl alcohol (FFA) coupled with the efficient co‐production of H 2 O 2 is reported, enabled by covalent organic frameworks (COFs) induced, 1 O 2 ‐participated Achmatowicz rearrangement. This study introduces…
Citation impact
- FWCI
- 22.72
- Percentile
- 100%
- References
- 81
Authors
5- QXQiang Xue
Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- HLHanxi Li
Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- PJPeng Jin
Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- XZXukai ZhouCorresponding
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences
- FWFeng Wang
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, University of Chinese Academy of Sciences
Topics & keywords
- Singlet oxygen
- Hydrogen peroxide
- Photocatalysis
- Biomass (ecology)
- Covalent bond
- Photochemistry
- Chemistry
- Coupling (piping)