articleNature CommunicationsMar 5, 2025GOLD OA

Solvent-regulable interfacial groups enable on-demand superhydrophobic/superhydrophilic silica aerogels

University of Science and Technology of China · Chinese Academy of Sciences · +2 more institutions

PubMed
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Abstract

Silica aerogel, as the earliest synthetic and commercially available one among all known aerogels, holds significant value in fields including thermal and acoustic insulation, optics, catalysis, sorption, etc. However, throughout its nearly century-long history, the influence of solvent used during synthesis on the properties of silica aerogels has been neglected, resulting in inaccurate and ambiguous performance evaluation. Herein, we have uncovered and systematically investigated the solvent-regulable interfacial groups that enable on-demand superhydrophobicity/superhydrophilicity of silica aerogels. During either sol-gel transition or solvent exchange process both required for aerogel synthesis, the…

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