articleAngewandte Chemie International EditionMar 11, 2025BRONZE OA

Synergistic Catalysts with Fe Single Atoms and Fe 3 C Clusters for Accelerated Oxygen Adsorption Kinetics in Oxygen Reduction Reaction

CLChunlian LiuRYRuizhe YangJWJiacheng WangBLBowen LiuXCXiaowan Chang

Guangzhou University · University of Electronic Science and Technology of China · +4 more institutions

PubMed
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Abstract

Abstract The design of cost‐effective and efficient catalysts based on transition metal–based electrocatalysts for the oxygen reduction reaction (ORR) is crucial yet challenging for energy‐conversion devices like metal–air batteries. In this work, we present a cost‐effective strategy for preparing catalysts consisting of single‐atomic Fe sites and Fe 3 C clusters encapsulated in nitrogen‐doped carbon layers (FeSA‐Fe 3 C/NC). The FeSA‐Fe 3 C/NC electrocatalyst demonstrates outstanding ORR performance in alkaline electrolytes, achieving a high half‐wave potential ( E 1/2 = 0.902 V), 4e − ORR selectivity, and robust methanol tolerance. The exceptional ORR catalytic performance is credited to the relatively…

Citation impact

79
total citations
FWCI
22.23
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100%
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62
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Authors

14

Topics & keywords

Keywords
  • Catalysis
  • Electrocatalyst
  • Electrolyte
  • Methanol
  • Materials science
  • Oxygen
  • Chemical engineering
  • Adsorption
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