articleAccounts of Chemical ResearchMar 12, 2025Closed access

Two-Dimensional Heteropore Covalent Organic Frameworks: From Construction to Functions

Chinese Academy of Sciences · Shanghai Institute of Organic Chemistry

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Abstract

ConspectusCovalent organic frameworks (COFs) represent a fascinating class of crystalline porous polymers constructed from organic building blocks linked by covalent bonds. Benefiting from their high crystallinity, large surface area, and ease of functionalization, COFs have demonstrated significant potential across various fields, including gas adsorption, luminescence, sensing, catalysis, energy storage, nanomedicine, etc. In the first decade of COF development, only those with homogeneous porosity have been constructed, and thus, their topological structures are quite limited. An exciting progress in the field of COFs is the emergence of two-dimensional (2D) COFs with hierarchical porosity, known as…

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