articleInfoMatMar 13, 2025GOLD OA

Addressing the interface issues of all‐solid‐state lithium batteries by ultra‐thin composite solid‐state electrolyte combined with the integrated preparation technology

University of Science and Technology Beijing · Guilin University of Technology

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Abstract

Abstract The interfacial engineering in solid‐state lithium batteries (SSLBs) is attracting escalating attention due to the profoundly enhanced safety, energy density, and charging capabilities of future power storage technologies. Nonetheless, polymer/ceramic interphase compatibility, serious agglomeration of ceramic particles, and discontinuous ionic conduction at the electrode/electrolyte interface seriously limit Li + transport in SSLBs and block the application and large‐scale manufacturing. Hence, garnet Li 7 La 3 Zr 2 O 12 (LLZO) nanoparticles are introduced into the polyacrylonitrile (PAN) nanofiber to fabricate a polymer‐ceramic nanofiber‐enhanced ultrathin SSE membrane (3D LLZO‐PAN), harnessing…

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