reviewChemical ReviewsMar 19, 2025Closed access

Strategies and Prospects for High-Performance Te-Free Thermoelectric Materials

Tan Kah Kee Innovation Laboratory · Materials Technologies (United States) · +3 more institutions

PubMed
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Abstract

Thermoelectric materials hold great potential for direct conversion of ubiquitous waste heat into electricity. However, their commercialization is hindered by low efficiency, reliance on rare and expensive Te, and limited stability under operating conditions. This review explores recent advances in novel strategies for achieving high thermoelectric performance and stability in Te-free inorganic bulk materials. First, we discuss diverse innovative techniques aimed at substantially enhancing electrical transport properties. These methods encompass strategies such as charge carrier engineering, band convergence, band inversion, valley anisotropy, multiband synglisis, and the incorporation of resonant levels or…

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