articleAngewandte Chemie International EditionMar 27, 2025BRONZE OA

Carbon and Oxygen Double Defects‐Enhanced Ru‐Based Catalyst for Ammonia Decomposition

Beijing University of Technology · Beijing University of Chemical Technology

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Abstract

Abstract Although ammonia is widely recognized as one of the most promising candidates for hydrogen storage and transformation, the catalytic mechanisms involved in ammonia decomposition remain insufficiently understood, and the stability of catalysts continues to present significant challenges. In this study, Ru/CeO 2 ‐CNTs catalysts with double defect sites were synthesized by a straightforward method, achieving an outstanding hydrogen production rate of 2230 mmol −1 g Ru −1 min −1 at 500 °C, outperforming most Ru‐based catalysts. Experimental characterization and theoretical calculations revealed that the CeO 2 ‐CNTs interface promotes the formation of oxygen vacancies (O v ) and carbon defects (C d )…

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