Facet Engineering of Metal‐Organic Frameworks for Triboelectric Nanogenerators‐Based Self‐Powered Water Splitting
Zhejiang University of Technology · South China University of Technology · +1 more institution
Abstract
Abstract Metal‐organic frameworks (MOFs) are highly versatile materials with tunable chemical and structural properties, making them promising for triboelectric nanogenerators (TENGs) and electrocatalysis. However, achieving precise control over MOF coordination structures to optimize facet‐dependent properties remains challenging. Here, a facile and scalable dual‐solvent synthesis strategy is presented to fabricate dendrite Co‐2‐methylimidazole MOF (ZIF‐67‐D), enabling tailored preferred facet and coordination environments. Using density functional theory (DFT) calculations and synchrotron‐based X‐ray absorption spectroscopy, it is demonstrated that ZIF‐67‐D, enriched with (112) facets, features a reduced Co…
Citation impact
- FWCI
- 24.42
- Percentile
- 100%
- References
- 50
Authors
8Topics & keywords
- Materials science
- Triboelectric effect
- Metal-organic framework
- Water splitting
- Facet (psychology)
- Nanotechnology
- Density functional theory
- Electrocatalyst
Funding
- NNNational Natural Science Foundation of ChinaAwards: 22275166, 52473050, 52173046
- FRFundamental Research Funds for the Central UniversitiesAward: 2024ZYGXZR080
- NSNatural Science Foundation of Zhejiang ProvinceAward: LZ21E030002
- FRFundamental Research Funds for the Provincial Universities of ZhejiangAward: RF‐B2024001：RF‐B2023002