Regulating Enol-to-Keto Tautomerization of Pillararene-Based Conjugated Macrocycle Polymers for H 2 O 2 Photosynthesis
Jilin University · State Key Laboratory of Inorganic Synthesis and Preparative Chemistry · +1 more institution
Abstract
. In-depth investigations reveal that the incorporation of pillararenes enables synergistic catalysis of water oxidation and oxygen reduction reactions and significantly enhances catalyst stability by regulating molecular tautomerization. This work opens new avenues for designing high-performance multifunctional conjugated macrocycle polymers with significant potential for clean energy conversion.
Citation impact
- FWCI
- 19.18
- Percentile
- 100%
- References
- 66
Authors
8- ZWZhuo-Qin WangCorresponding
Jilin University
- MLMenghao Li
Jilin University
- SLShuang Liang
Jilin University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
- YKYuxiang Kong
Jilin University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry
- CWChunyu Wang
Jilin University, State Key Laboratory of Supramolecular Structure and Materials
Topics & keywords
- Chemistry
- Tautomer
- Conjugated system
- Keto–enol tautomerism
- Enol
- Photosynthesis
- Polymer
- Stereochemistry