articleACS NanoApr 11, 2025Closed access

High-Entropy Conversion-Alloying Anode Material for Advanced Potassium-Ion Batteries

Northwestern Polytechnical University · University of Shanghai for Science and Technology · +1 more institution

PubMed
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Abstract

Conversion-alloying dual-mechanism materials are considered as promising anodes for potassium-ion batteries (KIBs) owing to multielectron transfer with high theoretical specific capacity and low operating voltage, whereas large lattice strain and sluggish kinetics hinder the rate and cyclability ability. Herein, a high-entropy telluride (HET, Sb1.4Bi0.2Sn0.2Co0.1Mn0.1Te3) is proposed as an advanced anode material for KIBs. The disordered coordination environment originated from high-entropy composition assists HET to eliminate band gap, enhance K-ion adsorption capability, and lower K-ion migration barrier, thereby contributing superior electrochemical dynamics behavior. It is verified that HET stores K-ion…

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