Low‐Redox‐Barrier Two‐Electron p‐Type Phenoselenazine Cathode for Superior Zinc‐Organic Batteries

Shi, Ting; Song, Ziyang; Hu, Chengmin; Huang, Qi; Lv, Yaokang; Miao, Ling; Gan, Lihua; Zhu, Dazhang; Liu, Mingxian

doi:10.1002/anie.202501278

articleAngewandte Chemie International EditionApr 11, 2025BRONZE OA

Low‐Redox‐Barrier Two‐Electron p‐Type Phenoselenazine Cathode for Superior Zinc‐Organic Batteries

TSTing Shi ZSZiyang Song CHChengmin Hu QHQi Huang YLYaokang Lv

Tongji University · Fudan University · +3 more institutions

PubMed

Indexed incrossrefpubmed

Abstract

Abstract Organic p‐type cathode materials with high redox potentials and fast kinetics have captured widespread attention in propelling Zn‐organic batteries (ZOBs). However, their anion‐accessible capacity is insufficient due to single electron reaction and/or high energy barrier of each redox‐active unit. Here, we design two‐electron‐donating p‐type organic chalcogen small molecules (phenoxazine (PO), phenothiazine (PS), and phenoselenazine (PSe)) with tuned charge distributions and electron transfer behaviors as cathode materials for ZOBs. With the decrease of chalcogenide electronegativity (O > S > Se), PSe liberates the strongest coordination activity, efficient electron delocalization, and charge…

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42

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FWCI: 24.29
Percentile: 100%
References: 96

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9

Topics & keywords

Topics

Keywords

Redox
Chemistry
Delocalized electron
Cathode
Electron transfer
Chalcogen
Organic radical battery
Electrochemistry

UN Sustainable Development Goals

Affordable and clean energy

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