articleAdvanced MaterialsApr 17, 2025Closed access

Dual Doping of N and F on Co 3 O 4 to Activate the Lattice Oxygen for Efficient and Robust Oxygen Evolution Reaction

University of Electronic Science and Technology of China · Huzhou University · +7 more institutions

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Abstract

Abstract The oxygen evolution reaction (OER) is a pivotal process in numerous renewable energy conversion technologies. However, its sluggish intrinsic kinetics and intricate transfer process impede the efficient conversion of energy. Activating the lattice oxygen mechanism (LOM) is of paramount importance to break through the theoretical scaling relationship and boost the oxygen evolution catalytic activity. In this contribution, N and F are successfully introduced into Co 3 O 4 simultaneously as heteroatoms via a controllable plasma strategy to modulate the covalency property of metal‐oxygen. Theoretical simulations and experiment results demonstrated that the covalency of the cobalt‐oxygen bond is…

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