articleConstruction and Building MaterialsApr 19, 2025HYBRID OA

Highly thermally stable MOF-based flame retardant system for fire-safe and toxicity-suppressing rigid polyurethane foam

Anhui Agricultural University · Anhui University · +3 more institutions

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Abstract

Metal-organic frameworks (MOF) as promising flame retardants are constrained in polymer applications due to their low thermal stability and mechanical strength. To tackle these challenges, biomass-modified steel slag (PSS) was utilized to develop a highly thermally stable MOF-based flame retardant system, designed to enhance the thermal stability, flame retardancy, and toxicity suppression properties of rigid polyurethane foam (RPUF). When combined with ammonium polyphosphate, the MOF flame retardant system significantly enhances the flame retardancy of RPUF, achieving the UL-94 V-0 rating. Cone calorimeter tests revealed that compared to pure RPUF, the total heat release values of RPUF/APP/MOF, RPUF/APP/PSS,…

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