articleAngewandte Chemie International EditionApr 22, 2025BRONZE OA

Precise Engineering of Asymmetric Tri‐Active Sites by Symbiotic Strategy for Photocontrolled Directional Reforming of Biomass

Guizhou University · Liaoning University · +6 more institutions

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Abstract

Abstract Sunlight‐driven production of high‐value chemicals from renewable resources represents a pivotal driver toward achieving sustainable energy supply. However, fundamental barriers include inadequate use of light energy and insufficient understanding of reactive oxygen species (ROS) regulating mechanisms in photocatalytic processes. To address this, a novel symbiotic strategy for the design of Cu x /TiO 2 single‐atom catalysts (SACs) supported by density functional theory (DFT) calculations was proposed. The developed catalyst achieved nearly 100% conversion and selectivity for the directional photooxidative transformation of 5‐hydroxymethylfurfural (HMF) to 2,5‐diformylfuran (DFF) or…

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78
total citations
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21.94
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100%
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70
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Authors

12

Topics & keywords

Keywords
  • Catalysis
  • Biomass (ecology)
  • Oxidative phosphorylation
  • Chemistry
  • Photocatalysis
  • Reactive oxygen species
  • Renewable energy
  • Photochemistry
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