articleAdvanced Functional MaterialsMay 5, 2025Closed access

Controllable‐Photocorrosion Balance Endows ZnCdS Stable Photocatalytic Hydrogen Evolution

XZXinlong ZhengYSYiming SongQGQizhi GaoJLJiaxin LinJZJiadi Zhai

Hainan University

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Abstract

Abstract Metal sulfide (MS) photocatalysts are highly attracted for visible‐light photocatalytic hydrogen evolution (PHE), yet the ubiquitous issue of photocorrosion significantly undermines their photostability, often viewed as a detrimental effect. In this study, the positive impact of controllable‐photocorrosion is highlighted on enhancing the PHE activity of MS photocatalysts. Specifically, it establish a clear structure‐activity relationship for ZnCdS solid solutions fabricated via a unique sulfur‐rich butyldithiocarbamic acid solution process. During the PHE process, the sulfur‐rich surface of ZnCdS not only efficiently scavenges excess photogenerated holes but also facilitates the accumulation of sulfur…

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54
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15.10
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100%
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Authors

12

Topics & keywords

Topics
Keywords
  • Materials science
  • Photocatalysis
  • Balance (ability)
  • Chemical engineering
  • Nanotechnology
  • Optoelectronics
  • Organic chemistry
  • Catalysis
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