Understanding the Electrochemical Window of Solid-State Electrolyte in Full Battery Application

Bai, Chen; Li, Yuhang; Xiao, Guanyou; Chen, Jiajing; Tan, Shendong; Shi, Peiran; Hou, Tingzheng; Liu, Ming; He, Yan‐Bing; Kang, Feiyu

doi:10.1021/acs.chemrev.4c01012

reviewChemical ReviewsMay 8, 2025Closed access

Understanding the Electrochemical Window of Solid-State Electrolyte in Full Battery Application

CBChen Bai YLYuhang Li GXGuanyou Xiao JCJiajing Chen STShendong Tan

Tsinghua–Berkeley Shenzhen Institute · Division of Materials Science and Engineering · +1 more institution

PubMed

Indexed incrossrefpubmed

Abstract

In recent years, solid-state Li batteries (SSLBs) have emerged as a promising solution to address the safety concerns associated. However, the limited electrochemical window (ECW) of solid-state electrolytes (SEs) remains a critical constraint full battery application. Understanding the factors that influence the ECW is an essential step toward designing more robust and high-performance electrochemical systems. This review provides a detailed classification of the various "windows" of SEs and a comprehensive understanding of the associated interfacial stability of SEs in full battery application. The paper begins with a historical overview of SE development, followed by a detailed discussion of their…

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51

total citations

FWCI: 29.80
Percentile: 100%
References: 741

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Authors

10

Topics & keywords

Topics

Keywords

Chemistry
Electrolyte
Electrochemistry
Battery (electricity)
Window (computing)
Solid-state
Electrochemical window
Nanotechnology

UN Sustainable Development Goals

Affordable and clean energy

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