articleAdvanced MaterialsMay 8, 2025Closed access

Interfacial Charge Transfer in ZnO/COF S‐Scheme Photocatalyst via Zn ─ N Bond

Wuhan University of Technology · China University of Geosciences · +3 more institutions

PubMed
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Abstract

Photocatalysis is a promising solution to global energy shortage and environmental problems. Inspired by photosynthesis, multicomponent heterostructured photocatalysts are extensively investigated, and step-scheme (S-scheme) heterojunction has emerged as the theoretical basis for delineating charge transfer processes in predominant heterostructured photocatalysts. However, the specific charge transfer pathway across an S-scheme heterojunction remains elusive from an atomic/molecular perspective. Herein, it is demonstrated that in S-scheme heterojunction photocatalysts composed of imine-based covalent organic frameworks and nanostructured zinc oxide, interfacial Zn─N bonds are formed between the two components…

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